Wednesday, 8 August 2012



The crystal structure of diamond is equivalent to a face-centred cubic (FCC) lattice, with a basis of two identical carbon atoms: one at (0, 0, 0) and the other at (1/4, 1/4, 1/4), where the coordinates are given as fractions along the cube sides. This is the same as two interpenetrating FCC lattices, offset from one another along a body diagonal by one-quarter of its length.

http://m-newton.ex.ac.uk/research/qsystems/people/sque.togo/diamond/structure/



The lattice describes the repeat pattern; for diamond cubic crystals this lattice is "decorated" with a motif of two tetrahedrally bonded atoms in each primitive cell, separated by 1/4 of the width of the unit cell in each dimension.Many compound semiconductors such as gallium arsenide, β-silicon carbide and indium antimonide adopt the analogous zincblende structure, where each atom has nearest neighbors of an unlike element. Zincblende's group is F43m, but many of its structural properties are quite similar to the diamond structure.

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   20.51, 8.08.12. 

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